32535-25-4Relevant academic research and scientific papers
Stereoisomeric Pd(II) complexes with serine, threonine, and allothreonine
Krylova,Kovtunova,Romanenko,Sheludyakova,Kurat'Eva
, p. 52 - 60 (2011)
The paper describes methods for the synthesis and isolation of solid phases of the individual stereoisomeric Pd(II) bis(amino acid) complexes with serine (SerH = NH2CH(CH2OH)COOH, α-amino-β- hydroxypropionic acid), threonine (ThrH CH3CH(OH)CH(NH 2)COOH, threo-α-amino-β-hydroxybutyric acid), and allothreonine (alloThrH is erythro-α-amino-β-hydroxybutyric acid): cis-[Pd(S-Ser)2], trans-[Pd(R-Ser)(S-Ser)], cis-[Pd(S-Thr)2], trans-[Pd(S-Thr)2], trans-[Pd(R-Thr)(S-Thr)], and cis-[Pd(R-alloThr)(S-alloThr)] (R, S are the absolute configurations of the asymmetric Catom connected to the NH2 group). The synthesized compounds were characterized by elemental analysis, IR and NMR (1H and 13C) data, and X-ray diffraction analysis.
Synthesis, characterization, and non-covalent interactions of palladium(Ii)-amino acid complexes
Berg, Michael A. G.,Hobart, David B.,Merola, Joseph S.,Rogers, Hannah M.
, (2021/07/31)
The reaction of palladium(II) acetate with acyclic amino acids in acetone/water yields square planar bis-chelated palladium amino acid complexes that exhibit interesting non-covalent interactions. In all cases, complexes were examined by multiple spectros
