32577-69-8

Upstream product

• 1717-42-6 ethyl (3-trifluoromethylbenzoyl)acetate 
• 2251-65-2 3-(Trifluoromethyl)benzoyl chloride 
• 93618-66-7 3-(3-trifluoromethylphenyl)-3-oxo-propionic acid methyl ester 
• 616-38-6 carbonic acid dimethyl ester 
• 349-76-8 3'-(trifluoromethyl)acetophenone 

Downstream Products

• 64300-33-0 5-ethoxy-3-(4-methoxy-phenyl)-isoxazole 
• 64300-32-9 5-ethoxy-3-(3-trifluoromethyl-phenyl)-isoxazole 
• 1352952-15-8 4-(2,4,6-trimethylbenzylidene)-3-(3-trifluoromethylphenyl)-1,2-oxazol-5(4H)-one 

Relevant academic research and scientific papers

Palladium Catalyzed Ring Expansion Reaction of Isoxazolones with Isocyanides: Synthesis of 1,3-Oxazin-6-One Derivatives

A palladium catalyzed ring expansion reaction of isoxazolones with isocyanides was disclosed. In the reaction, a cascade process involving ring-opening/cyclization was suggested. The reaction features high atomic economy due to no elimination of CO2 occurred. Moreover, products obtained demonstrate aggregation-induced emission properties with relatively high solid-state emission efficiencies. (Figure presented.).

Palladium catalyzed insertion reaction of isocyanides with 3-arylisoxazol-5(4 H)-ones: Synthesis of 4-aminomethylidene isoxazolone derivates

A palladium catalyzed insert reaction of isocyanides to 3-arylisoxazol-5(4H)-ones for the construction of 4-aminomethylidene isoxazolone derivates is reported. In this transformation, only the C-H bond of the methylene group was involved while the remaining ring structure was retained. In general, this work provided a new protocol for the synthesis of 4-aminomethylidene isoxazolones.

3-Aryl-4-(2,6-dimethylbenzylidene)isoxazol-5(4H)-ones as Fungicides

The invention relates to 3-aryl-4-(2,6-dimethylbenzylidene)isoxazol-5(4H)-ones, to agrochemically active salts thereof, to the use thereof and to methods and compositions for controlling phytopathogenic harmful fungi and insects in and/or on plants or in