326-17-0Relevant academic research and scientific papers
Oxidation of fluoroanilines to fluoroazobenzenes with potassium ferricyanide and KOH
Leyva, Elisa,Monreal, Elena,Medina, Concepcion,Leyva, Socorro
, p. 7847 - 7848 (2007/10/03)
The oxidation of several fluoroanilines to fluoroazobenzenes with potassium ferricyanide and KOH in a solvent mixture of ethanol/water is described.
Photochemistry of Fluorinated Aryl Azides in Toluene Solution and in Frozen Polycrystals
Leyva, Elisa,Munoz, Daniel,Platz, Matthew S.
, p. 5938 - 5945 (2007/10/02)
Several fluorinated triplet aryl nitrenes have been generated in low-temperature polycrystals by photolysis of the corresponding azides.Upon extended photolysis at -196 deg C the nitrenes abstract hydrogen from frozen toluene to give anilino-benzyl radical pairs, which subsequently combine to give CH insertion products.The radical pairs and the triplet nitrenes have been detected by EPR.In toluene solution, the major reaction products are tar, the corresponding fluorinated anilines, and azo compounds.
