32612-68-3

Basic information

• Product Name: (η5-cyclopentadienyl)iridium(carbonyl)(triphenylphosphine)
• Synonyms: (η5-cyclopentadienyl)iridium(carbonyl)(triphenylphosphine)
• CAS NO: 32612-68-3
• Molecular Weight: 547.616
• Mol File: 32612-68-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (η5-cyclopentadienyl)iridium(carbonyl)(triphenylphosphine)(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-cyclopentadienyl)iridium(carbonyl)(triphenylphosphine)(32612-68-3)
• EPA Substance Registry System: (η5-cyclopentadienyl)iridium(carbonyl)(triphenylphosphine)(32612-68-3)

Safety Data

• Hazardous Substances Data: 32612-68-3(Hazardous Substances Data)

Upstream product

• 15318-31-7 bis(triphenylphosphine)iridium(I) carbonyl chloride 
• 157773-16-5 (η(5)-chlorocyclopentadienyl)dicarbonyliridium 
• 59246-46-7 bis(triphenylphosphine)carbonyliridium(I) chloride 
• 59952-74-8 cis-Ir(CO)2Cl(p-NH₂C₆H₄CH₃) 
• 542-92-7 cyclopenta-1,3-diene 
• 603-35-0 triphenylphosphine 

Downstream Products

• 144497-03-0 Ir(CO)(P(C₆H₅)3)3⁽¹⁺⁾*SO₃CF₃^(1-)={Ir(CO)(P(C₆H₅)3)3}SO₃CF₃ 
• 47558-18-9 (C₅H₅)Ir(CO)(P(C₆H₅)3)(CH₃)⁽¹⁺⁾*I^(1-)=[(C₅H₅)Ir(CO)(P(C₆H₅)3)(CH₃)]I 
• 15318-31-7 bis(triphenylphosphine)iridium(I) carbonyl chloride 
• 103731-57-3 (η5-C5H5)(PPh3)Ir(η2-C(p-ClC6H4)NOC(O)) 
• 103731-58-4 (η5-C5H5)(PPh3)Ir(η2-C(p-FC6H4)NOC(O)) 

Relevant articles and documents

Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp'Ir(CO)(PR3) Complexes

Basicities of the series of complexes CpIr(CO)(PR3) [PR3 = P(p-C6H4CF3)3 P(p-C6H4F)3, P(p-C6H4Cl)3, PPh3, P(p-C

Heats of protonation of transition-metal complexes: The effect of phosphine basicity on metal basicity in CpIr(CO)(PR3) and Fe(CO)3(PR3)2

Titration calorimetry has been used to determine the effects of phosphine ligand basicity on the heats of protonation (ΔHHM) of the metal in the CpIr(CO)(PR3) and Fe(CO)3(PR3)2complexes (PR3/sub