32621-99-1

Basic information

• Product Name: [3,3']Bi[tricyclo[4.3.1.1^3,8]undecyl]
• CAS NO: 32621-99-1
• Molecular Weight: 298.512
• Mol File: 32621-99-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [3,3']Bi[tricyclo[4.3.1.1^3,8]undecyl](CAS DataBase Reference)
• NIST Chemistry Reference: [3,3']Bi[tricyclo[4.3.1.1^3,8]undecyl](32621-99-1)
• EPA Substance Registry System: [3,3']Bi[tricyclo[4.3.1.1^3,8]undecyl](32621-99-1)

Safety Data

• Hazardous Substances Data: 32621-99-1(Hazardous Substances Data)

Upstream product

• 27011-47-8 homoadamantanyl chloride 

Relevant articles and documents

High-Yield Direct Synthesis of a New Class of Tertiary Organolithium Derivatives of Polycyclic Hydrocarbons

For the first time, 1- and 2-adamantyllithium, 1-diamantyllithium, 3,5,7-trimethyl-1-adamantyllithium, 1-twistyllithium, 3-methyl-7-noradamantyllithium, 1-triptycyllithium, and 3-homoadamantyllithium have been directly synthesized from the reaction of an organic halide and lithium metal.By use of certain experimental parameters, the phenomena at the metal-solution interface are controlled, thereby resulting in exceptionally high yields of this new class of organometallic compounds (>75percent, except in the case of 3-homoadamantyllithium).Competition between formation of the organometallic compound and formation of solvent-attack byproducts is determined by the degree of adsorption of the transient species (anion radical RX-. or radical pair R..Li) generated at the metal surface during attack by the halogenated derivative.