326471-52-7Relevant academic research and scientific papers
Total synthesis of achaetolide from D-mannitol
Rao, K. Sripad,Chattapadhyay, Amit Kumar,Ghosh, Subhash
scheme or table, p. 3078 - 3080 (2011/02/25)
A highly convergent stereoselective total synthesis of achaetolide, a ten-membered lactone is described. The ring-closing metathesis reaction was used to construct the macrocycle and E-olefinic moiety in the molecule. The key acid and alcohol fragments we
Synthetic studies on pectenotoxins: Synthesis of the common C8-C18 THF fragment
Awakura,Fujiwara,Murai
, p. 1733 - 1736 (2007/10/03)
The stereoselective synthesis of the common C8-C18 THF fragment of pectenotoxins is reported. The THF ring was constructed by the ring closure of the epoxide possessing all six asymmetric centers with a 5-exo-mode. These stereogenic centers were arranged successively from the enantiomerically active epoxide by utilizing the stereo-differentiating influence of the proximal functional groups.
