3267-96-7Relevant academic research and scientific papers
Compounds containing a monovalent metal cation, an organic anion, and an α,α′-dioximino cyclic ketone
Ferris, Arthur F.,Salerni, O. Leroy
, p. 1721 - 1724 (2008/10/08)
A new and unusual class of compounds containing a monovalent metal ion, an organic anion, and a 2,6-dioximinocyclohexanone in a 1:1:1 mole ratio has been discovered. Sodium, potassium, and silver cations gave compounds of this type ; rubidium gave compounds containing also two moles of water. Only aromatic sulfonate anions participated in compound formation with the alkali metal cations, whereas with silver cation, aromatic sulfonate, phenylphosphonate, and trifluoroacetate anions all gave compounds. 2,5-Dioximinocyclopentanone formed compounds with aromatic sulfonate anions and silver cation, but not with alkali metal cations. These compounds contained 2,5-dioximinocyclopentanone, anion, cation, and water in a 1:1:1:1 mole ratio. All the compounds of 2,6-dioximinocyclohexanones appeared to exist only in the solid state and to be completely dissociated in solution.
