326892-19-7Relevant academic research and scientific papers
Rhodium and palladium complexes from 1,1′ and 1,2 ferrocenylphosphine as bidentate ligands. Versatile coordination
Broussier, Roland,Bentabet, Emmanuelle,Laly, Myriam,Richard, Philippe,Kuz'mina, Lyudmila G.,Serp, Philippe,Wheatley, Nigel,Kalck, Philippe,Gautheron, Bernard
, p. 77 - 85 (2007/10/03)
The complexation of the mixed bidentate ligands 1-diphenylphosphino-1′-diphenylthiophosphinoferrocenyl and 1,2-bis-(diphenylphosphino)ferrocenyl with rhodium(I) and palladium(II) species yield a range of mono- and dirhodium or palladium complexes. Their interest as possible catalysts for alkene hydroformylation and alkoxycarbonylation and Heck coupling reactions has been assessed. Fe[C5Me4P(S)Ph2][C5Me 4PPh2]PdCl2 and Fe[C5H2-1,2-(PPh2)2-4- tBu][C5H5]PdCl2 have been characterized by single-crystal X-ray diffraction studies.
