327155-46-4Relevant academic research and scientific papers
Palladium-catalyzed addition of alcohol pronucleophiles to alkylidenecyclopropanes
Camacho,Nakamura,Saito,Yamamoto
, p. 270 - 275 (2007/10/03)
Palladium-catalyzed addition of alcohol pronucleophiles 1 to alkylidenecyclopropane derivatives afforded the corresponding allylic ethers 3 in excellent to moderate yields. Catalyst optimization indicated the Pd(PPh3)4-P(o-tolyl)3 combination as the best system among all catalysts tested. Intramolecular reaction also proceeded smoothly. A plausible mechanism for this catalytic reaction was proposed.
