327621-99-8

Basic information

• Product Name: [(C₅H₅N)B₈H₁₁NHEt]
• Synonyms: [(C₅H₅N)B₈H₁₁NHEt]
• CAS NO: 327621-99-8
• Molecular Weight: 220.753
• Mol File: 327621-99-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₅H₅N)B₈H₁₁NHEt](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₅H₅N)B₈H₁₁NHEt](327621-99-8)
• EPA Substance Registry System: [(C₅H₅N)B₈H₁₁NHEt](327621-99-8)

Safety Data

• Hazardous Substances Data: 327621-99-8(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 61289-01-8 [(EtH₂N)B₈H₁₁NHEt] 

Relevant articles and documents

Synthesis of N-substituted derivatives of the hypho-(amine)(amino)B8H11 system

The chemistry of the hypho-(amine)(amino)B8H11 system is developed by the synthesis of several derivatives by three routes. [(Et2HN)B8H11NEt2] (4), characterised by single-crystal X-ray work, is prepared from the reaction between B9H13(SMe2) and Et2NH. Methylation of [(EtH2N)B8H11NHEt] (1) using NaH and MeI gives, successively, [(EtMeHN)B8H11NHEt] (5), [(EtMe2N)B8H11NHEt] (6) and [(EtMe2N)B8H11NMeEt] (7). Alternatively, a displacement reaction with NHEt2 on (1) or on [(MeH2N)B8H11NHMe] (2) yields [(Et2HN)B8H11NHEt] (8) or [(Et2HN)B8H11NHMe] (9), and a displacement on (1) with pyridine yields [(C5H5N)B8H11NHEt] (10). Phosphine-containing derivatives [(Ph3P)B8H11NHEt] (11) and [(PhMe2P)B8H11NHEt] (12) can be isolated from interaction of (1) with PPh3, [RhCl(PPh3)3] or [PtCl2(PMe2Ph)2].