327628-32-0

Upstream product

• 18001-18-8 allyldimethylphenylsilane 
• 99438-28-5 (+)-B-methoxydiisocamphenylborane 

Downstream Products

• 263888-03-5 (2R,3S)-1-Benzyloxy-3-(dimethyl-phenyl-silanyl)-pent-4-en-2-ol 
• 133285-26-4 (3R,4S)-3-(dimethylphenyl)silylnon-1-ene-4-ol 
• 133285-26-4 (3S,4R)-3-(dimethylphenyl)silylnon-1-ene-4-ol 
• 538334-67-7 (3S,4R,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)octa-1,7-dien-4-ol 
• 863604-39-1 (2R,4R,5S)-5-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-4-(dimethylphenylsilanyl)tetrahydrofuran-2-carbaldehyde 
• 863604-46-0 (2R,4R,5S)-[5-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-4-(dimethylphenylsilanyl)tetrahydrofuran-2-yl]methanol 
• 538334-76-8 (1R,2S,3R,4S,5S,6R)-5,6-dibenzyloxy-4-(tert-butyldimethylsilyloxy)-3-(dimethylphenylsilanyl)cyclohexane-1,2-diol 
• 538334-77-9 (1S,2R,3R,4S,5S,6R)-5,6-dibenzyloxy-4-(tert-butyldimethylsilyloxy)-3-(dimethylphenylsilanyl)cyclohexane-1,2-diol 
• 538334-73-5 (2R,3S,4R,5R)-4,5-dibenzyloxy-3-(tert-butyldimethylsilyloxy)-2-(dimethylphenylsilanyl)cyclohexene 
• 538334-65-5 (1S,2S,3S,4R,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)cyclohexane-1,2,4-triol 
• 538334-74-6 (1R,2S,3R,4S,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)cyclohexane-1,2,4-triol 

Relevant academic research and scientific papers

[3 + 2]-Annulation reactions of chiral allylsilanes and chiral aldehydes. Studies on the synthesis of bis-tetrahydrofuran substructures of annonaceous acetogenins

Double asymmetric [3 + 2]-annulation reactions of chiral β-silyloxylallylsilanes with chiral 2-tetrahydrofuranyl carboxaldehydes have been studied, leading to the stereocontrolled synthesis of six diastereomeric bis-tetrahydrofuran structures correspondin

[(E)-γ-(Dimethylphenylsilyl)allyl]diisopinocampheylborane: A highly enantioselective reagent for the synthesis of anti-β-hydroxyallylsilanes

anti-β-Hydroxyallylsilanes are prepared with 88-95% e.e. via the asymmetric allylboration reactions of aldehydes and [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocampheylborane (7). (C) 2000 Published by Elsevier Science Ltd.