32767-59-2Relevant articles and documents
Synthesis of thiazolidines via regioselective addition of unsymmetric thioureas to maleic acid derivatives
Pankova, Alena S.,Samartsev, Mikhail A.,Shulgin, Igor A.,Golubev, Pavel R.,Avdontceva, Margarita S.,Kuznetsov, Mikhail A.
, p. 51780 - 51786 (2014/12/10)
A wide range of unsymmetric thioureas has been studied in reaction with N-arylmaleimides and maleic anhydride. The regioselectivity of the addition depends not only on steric factors but on both solvent polarity and type of maleic acid derivative (imide o
Reagent-installed capsule network: Selective thiocarbamoylation of aromatic amines in crystals with preinstalled CH3NCS
Inokuma, Yasuhide,Ning, Guo-Hong,Fujita, Makoto
supporting information; experimental part, p. 2379 - 2381 (2012/05/04)
Crystalline reagent capsules were prepared by installing CH3NCS into networked molecular capsules. While the tight encapsulation completely prevented leaching of reagent molecules into the supernatant, introduction of amines into the interstitial pores triggered reagent delivery. As a result, enhanced substrate selectivity was observed in crystalline-state thiocarbamoylation (see picture; 86:14 in favor of 2- vs. 1-naphthylamine). Copyright