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Cyclohexyl 3-trifluoromethylphenyl ketone is an organic compound with the molecular formula C13H15F3O. It is a ketone derivative, characterized by the presence of a carbonyl group (C=O) bonded to a cyclohexyl group and a 3-trifluoromethylphenyl group. This chemical is known for its unique properties, such as its low reactivity due to the electron-withdrawing nature of the trifluoromethyl group, which makes it a valuable intermediate in the synthesis of various pharmaceuticals and agrochemicals. The compound is also recognized for its potential applications in the development of new materials and as a precursor in the production of specialty chemicals. Its stability and reactivity make it a subject of interest in organic chemistry research and industrial applications.

3277-77-8

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3277-77-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3277-77-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,2,7 and 7 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 3277-77:
(6*3)+(5*2)+(4*7)+(3*7)+(2*7)+(1*7)=98
98 % 10 = 8
So 3277-77-8 is a valid CAS Registry Number.
InChI:InChI=1/C14H15F3O/c15-14(16,17)12-8-4-7-11(9-12)13(18)10-5-2-1-3-6-10/h4,7-10H,1-3,5-6H2

3277-77-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclohexyl-[3-(trifluoromethyl)phenyl]methanone

1.2 Other means of identification

Product number -
Other names CYCLOHEXYL 3-TRIFLUOROMETHYLPHENYL KETONE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3277-77-8 SDS

3277-77-8Downstream Products

3277-77-8Relevant academic research and scientific papers

Direct C-H Arylation of Aldehydes by Merging Photocatalyzed Hydrogen Atom Transfer with Palladium Catalysis

Chen, Guangying,Cheng, Gui-Juan,Guo, Bin,Li, Xiaobao,Ran, Chongzhao,Wang, Lu,Wang, Ting,Wei, Jun-Jie,Zheng, Caijuan,Zheng, Chao

, p. 7543 - 7551 (2020/08/21)

Herein, we report that merging palladium catalysis with hydrogen atom transfer (HAT) photocatalysis enabled direct arylations and alkenylations of aldehyde C-H bonds, facilitating visible light-catalyzed construction of a variety of ketones. Tetrabutylammonium decatungstate and anthraquinone were found to act as synergistic HAT photocatalysts. Density functional theory calculations suggested a Pd0-PdII-PdIII-PdI-Pd0 pathway and revealed that regeneration of the Pd0 catalyst and the photocatalyst occurs simultaneously in the presence of KHCO3. This regeneration features a low energy barrier, promoting efficient coupling of the palladium catalytic cycle with the photocatalytic cycle. The work reported herein suggests great promise for further applications of HAT photocatalysis in palladium-catalyzed cross-coupling and C-H functionalization reactions to be successful.

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