327999-85-9

Basic information

• Product Name: triethyl(1-(p-tolyl)ethyl)silane
• Synonyms: triethyl(1-(p-tolyl)ethyl)silane
• CAS NO: 327999-85-9
• Molecular Weight: 234.457
• Mol File: 327999-85-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: triethyl(1-(p-tolyl)ethyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: triethyl(1-(p-tolyl)ethyl)silane(327999-85-9)
• EPA Substance Registry System: triethyl(1-(p-tolyl)ethyl)silane(327999-85-9)

Safety Data

• Hazardous Substances Data: 327999-85-9(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 60672-33-5 4-methyl-N'-(1-(p-tolyl)ethylidene)benzenesulfonohydrazide 
• 622-97-9 1-ethenyl-4-methylbenzene 

Relevant articles and documents

Palladium(0)-catalyzed C(sp3)-Si bond formation: Via formal carbene insertion into a Si-H bond

Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp3)-Si bond formation. The reaction, which uses readily available N-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(ii) and Cu(i) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(ii) carbene migratory insertion/reductive elimination mechanism is proposed.