328027-50-5Relevant academic research and scientific papers
Synthesis and IR spectral study of MoO2Cl2 molecular complexes with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine
Abramenko,Sergienko,Churakov
, p. 866 - 871 (2000)
A series of MoO2Cl2 complexes with acetoacetanilide derivatives were synthesized and studied by IR spectroscopy. The crystal and molecular structures of the MoO2Cl2 complex with acetoacet-2-toluidine (HL) were determined by X-ray diffraction analysis. The monoclinic crystals involved are a = 7.621(7) A, b = 9.498(3) A, c = 19.980(9) A, β = 95.16(7)°, V = 1440(2) A3, Z = 4, and space group P21/n. The coordination polyhedron of the Mo atom is a distorted octahedron with two O oxoatoms in the cis-position relative to each other, two Cl atoms in the trans-positions, and two O atoms (HL) in the trans-positions to O(oxo).
