328063-65-6

Basic information

• Product Name: [Co(1-phenylacetyl-4-phenyl-3-thiosemicarbazide)Cl₂]
• CAS NO: 328063-65-6
• Molecular Weight: 415.269
• Mol File: 328063-65-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Co(1-phenylacetyl-4-phenyl-3-thiosemicarbazide)Cl₂](CAS DataBase Reference)
• NIST Chemistry Reference: [Co(1-phenylacetyl-4-phenyl-3-thiosemicarbazide)Cl₂](328063-65-6)
• EPA Substance Registry System: [Co(1-phenylacetyl-4-phenyl-3-thiosemicarbazide)Cl₂](328063-65-6)

Safety Data

• Hazardous Substances Data: 328063-65-6(Hazardous Substances Data)

Upstream product

• 18233-63-1 N⁴-phenyl-phenylacetic acid thio-semicarbazide 
• 7646-79-9 cobalt(II) chloride 

Relevant articles and documents

Synthesis, Spectral, Magnetic and Thermal Studies of 1-Phenylacetyl-4-phenyl-3-thiosemicarbazide Complexes

Complexes of 1-phenylacetyl-4-phenyl-3-thiosemicarbazide (H2PAPTS) with Mn(ll), Fe(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Pd(II), Cd(II) and Hg(II) have been prepared and characterized on the basis of chemical, thermal (TG, DTA) analyses, spectral (IR, (1)H NMR, UV-Vis.), magneticmoment and molar conductivity measurements. IR and (1)H NMR spectral da ta show that H2PAPTS behaves as a neutral bidentate, mononegative bidentate or binegative tetradentate ligand. All the reported complexes are non-electrolytes and different stereochemistries are proposed for the Mn(II), Fe(II), Fe(III), Co(II), Ni(II), Cu(II) and Pd(II) complexes according to their magnetic and spectral measurements. The thermal decomposition of the complexes [Co(HPAPTS)(OAc)] and [Cd(HPAPTS)(OAc)(H2O)2] suggests a mechanism for their degradation. The [Fe(PAPTS)Cl(H2O)] complex was found to function as a one-electron sloichiometric oxidant towards primary and secondary alcohols.