32824-34-3

Basic information

• Product Name: (C₅H₅)(P(CH₃)(C₆H₅)2)CoCO
• Synonyms: (C₅H₅)(P(CH₃)(C₆H₅)2)CoCO
• CAS NO: 32824-34-3
• Molecular Weight: 352.318
• Mol File: 32824-34-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (C₅H₅)(P(CH₃)(C₆H₅)2)CoCO(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)(P(CH₃)(C₆H₅)2)CoCO(32824-34-3)
• EPA Substance Registry System: (C₅H₅)(P(CH₃)(C₆H₅)2)CoCO(32824-34-3)

Safety Data

• Hazardous Substances Data: 32824-34-3(Hazardous Substances Data)

Upstream product

• 79931-94-5 bis(μ-carbonyl)(μ-o-xylylene)bis[(η-cyclopentadienyl)cobalt] 
• 1486-28-8 diphenyl(methyl)phosphine 
• 12078-25-0 dicarbonylcyclopentadienylcobalt 

Downstream Products

• 126666-32-8 (C₅H₅)(P(CH₃)(C₆H₅)2)(CoCOCHC(C₆H₅)O) 
• 12078-25-0 dicarbonylcyclopentadienylcobalt 

Relevant articles and documents

Reaction of Cp3U=CHPMeRPh with CpCo(CO)2

A terminal carbonyl of CpCo(CO)2 inserts into the U=C bond of Cp3U=CHPMeRPh (R = Ph or Me) to produce Cp(OC)CoC(OUCp3)=CHPMeRPh. The structure of Cp(OC)CoC(OUCp3)=CHPMe2Ph has been confirmed by X-ray diffraction: space group P212121; a = 15.645 (2) ?, b = 23.828 (3) ?, c = 15.140 (3) ?, α = β= γ = 90°; final error indexes R = 0.0555, RG = 0.0644 for 3433 unique data with I > 3σ(I). Heating Cp(OC)CoC(OUCp3)=CHPMeRPh leads to the formation of Cp(OC)CoPMeRPh.