328386-14-7

Upstream product

• 4163-60-4 β-D-galactose peracetate 
• 328386-12-5 (1R,3S,4R,5R)-4-(Benzyl-benzyloxy-amino)-3-{(R)-hydroxy-[(2S,3S,4S,5S,6R)-3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-methyl}-6,8-dioxa-bicyclo[3.2.1]octan-2-one 
• 328386-10-3 1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose 
• 328386-09-0 (2R,3S,4R,5S,6S)-3,4,5-Tris-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-propa-1,2-dienyl-tetrahydro-pyran 
• 328386-07-8 2,3,4,6-Tetra-O-[(tert-butyl)dimethylsilyl]-C-β-D-galactopyranosylformaldehyde 
• 328386-08-9 1,3,4,5-tetra-O-acetyl-2,6-anhydro-7,8,9-trideoxy-L-glycero-D-allo-nona-7,8-dienitol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 4383-24-8 N,O-dibenzylhydroxylamine 
• 4551-15-9 phenylthiotrimethylsilane 
• 328386-13-6 (1R,2R,3R,4R,5R)-4-(Benzyl-benzyloxy-amino)-3-{(R)-hydroxy-[(2S,3S,4S,5S,6R)-3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-methyl}-6,8-dioxa-bicyclo[3.2.1]octan-2-ol 

Relevant academic research and scientific papers

Synthesis of a C-disaccharide analog of the Thomsen-Friedenreich (T) epitope

The 2,3,4,6-tetra-O-[(tert-butyl)dimethylsilyl]-C-β -D-galactopyranosylformaldehyde (2,6-anhydro-1,3,4,6-tetra-O-[(tert-butyl)dimethylsilyl] -D-glycero-L-manno-heptose, 2) was condensed with isolevoglucosenone (3) in the presence of Et2AlI to give 1,6-anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl] -D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy- β-D-glycero-hex-2-enopyranos-4-ulose (8). Diastereoselective conjugate addition of BnONHBn to 8, followed by diastereoselective ketone reduction with LiBH4 and treatment with Me3SiSPh/ZnI2 provided phenyl 3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O[(tert-butyl)dimethylsilyl]-D-glycero-L- manno-heptitol-1-C-yl}-2-[(N-benzoxyl-N-benzyl)amino]-2,3 -dideoxy-1-thio-β-D-galacto-hexopyranoside (14).