328539-28-2Relevant articles and documents
Synthesis and structure of novel arene chromium complexes with normal thiophosphorous esters as ligands
Milyukov,Zverev,Podlesnov,Krivolapov,Litvinov,Gubaidullin,Kataeva,Ginzburg,Sinyashin
, p. 698 - 703 (2007/10/03)
Reaction of ArCr(CO)3 with normal thiophosphorous esters P(SR)3 under conditions of "indirect" photochemical substitution gave a series of novel chromium complexes ArCr(CO)2P(SR)3, whose structure was proved by NMR and IR spectroscopy. X-ray diffraction was used to find that the phosphorothioite ligand in dicarbonyl(mesitylene)(triphenyl phosphorotrithioite)chromium in crystal has a conformation with the phenylthio groups cis, gauche, and trans to the Cr-P bond. This conformation is radically different from those characteristic of "free" phosphorothioites.
