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32894-82-9

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32894-82-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 32894-82-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,8,9 and 4 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 32894-82:
(7*3)+(6*2)+(5*8)+(4*9)+(3*4)+(2*8)+(1*2)=139
139 % 10 = 9
So 32894-82-9 is a valid CAS Registry Number.

32894-82-9Downstream Products

32894-82-9Relevant articles and documents

In water alkylation of amines with alcohols through a borrowing hydrogen process catalysed by ruthenium nanoparticles

Risi, Caterina,Calamante, Massimo,Cini, Elena,Faltoni, Valentina,Petricci, Elena,Rosati, Filippo,Taddei, Maurizio

, p. 327 - 331 (2020)

A simple and environmentally benign procedure for the synthesis of secondary amines in water has been developed. Combining Ru3(CO)12, tetraphenylcyclopentadienone and a small quantity of TGPS-750-M surfactant, primary and secondary alcohols were alkylated at N employing equimolar amounts of aromatic amines in water. The reaction occurs under microwave (MW) dielectric heating with high conversion and high yield. When required, the use of biomass-derived 2-MeTHF or GVL as a co-solvent is possible. Under the influence of MWs, a Ru nanoparticle-nanomicelle combination was formed acting as an effective and recyclable catalyst. This protocol was also employed for "in water" cyclisation to synthesise biologically relevant pyrrolobenzodiazepines (PBDs).

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