329015-93-2

Basic information

• Product Name: Pt[N(CONH₂)COCH(CN)](P(C₆H₅)3)2
• CAS NO: 329015-93-2
• Molecular Weight: 844.748
• Mol File: 329015-93-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt[N(CONH₂)COCH(CN)](P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pt[N(CONH₂)COCH(CN)](P(C₆H₅)3)2(329015-93-2)
• EPA Substance Registry System: Pt[N(CONH₂)COCH(CN)](P(C₆H₅)3)2(329015-93-2)

Safety Data

• Hazardous Substances Data: 329015-93-2(Hazardous Substances Data)

Upstream product

• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 1448-98-2 N-(aminocarbonyl)-2-cyano-acetamide 

Relevant articles and documents

Synthesis and characterisation of four-membered ring platinalactam complexes derived from 2-cyanoacetylurea; crystal structure of [Pt{N(CONH2)C(O)CH(CN)}(PPh3)2]

The reactions of cis-[PtCl2L2] [L = PPh3 or L2 = dppe (Ph2PCH2CH2PPh2)] with cyanoacetylurea [NCCH2C(O)NHC(O)NH2] and triethylamine gives the platinalactam complexes [Pt{N(CONH2)C(O)CH(CN)}L2]. A single-crystal X-ray diffraction study on the triphenylphosphine complex confirms the presence of the four-membered platinalactam ring; the urea substituent is involved in intra- and intermolecular hydrogen bonding, forming a dimer in the solid state.