329042-34-4Relevant academic research and scientific papers
Synthesis of the first 2,3-dihydro-1,2,3-azadiphosphete complex
Ionescu,Jones,Streubel
, p. 2204 - 2205 (2007/10/03)
Synthesis of the first 2,3-dihydro-1,2,3-azadiphosphete complex was achieved via thermal reaction of a 2H-azaphosphirene complex in o-xylene, whereby a 2,5-dihydro-1,3-diaza-2,5-diphosphinine complex and a further unidentified byproduct were formed; the structure of the title compound was established through an X-ray singlecrystal diffraction study.
Unexpected dimerisation of a 2H-azaphosphirene complex
Streubel,Wilkens,Ruthe,Jones
, p. 2453 - 2454 (2007/10/03)
Heating a 2H-azaphosphirene complex in the solid state afforded the first head-to-tail dimer, a 2,5-dihydro-2,5-diphosphapyrimidine complex, a η1-diphosphene complex and another complex having low-coordinated phosphorus centers; whereas the latter was detected only by 31P NMR spectroscopy, the dimer was isolated and structurally characterized.
