329796-99-8

Upstream product

• 3132-99-8 m-bromobenzoic aldehyde 
• 1730-25-2 allylmagnesium bromide 
• 24850-33-7 allyltributylstanane 
• 55137-94-5 triallyltin bromide 
• 2039-86-3 3-bromostyrene 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 106-95-6 allyl bromide 
• 107-37-9 allyltrichlorosilane 

Downstream Products

• 1351619-39-0 C₁₃H₁₄BrNO 
• 1351619-40-3 C₂₂H₂₉BrO₇ 
• 1351619-56-1 C₂₂H₃₃BrO₇ 
• 1351619-42-5 C₂₀H₃₁BrO₆ 
• 1351619-36-7 C₃₄H₆₅BrO₆Si₃ 
• 1351619-58-3 C₆₅H₁₁₇BrO₁₄Si₄ 
• 1351619-35-6 C₄₁H₅₉BrO₁₃ 
• 1351619-45-8 C₄₇H₇₀O₁₃ 
• 1351619-46-9 C₄₂H₆₀O₁₄ 
• 1351619-49-2 C₄₂H₆₂O₁₄ 
• 1351619-51-6 C₄₂H₆₀O₁₅ 

Relevant academic research and scientific papers

A chiral oxazoline for catalytic enantioselective Nozaki-Hiyama-Kishi allylation and vinylation of aldehydes

Asymmetric allylation and vinylation of aldehydes with allyl halides and vinyl halides have been achieved using the chromium(II)-oxazoline catalyst. The catalyst promotes the highly efficient enantioselective Nozaki–Hiyama-Kishi (NHK) allylation of aldehydes using allyl bromide, producing the corresponding homoallylic alcohols in good yields (up to 84%) and a high level of enantioselectivity (up to 98% ee). Meanwhile, the NHK vinylation of aldehydes produce desired allylic alcohols in satisfactory yields (up to 88%) and a high level of enantioselectivity (up to 97% ee). We developed a reliable and milder protocol for preparing chiral homoallylic and allylic alcohols.

Axial-Chiral Biisoquinoline N, N′-Dioxides Bearing Polar Aromatic C-H Bonds as Catalysts in Sakurai-Hosomi-Denmark Allylation

The design, synthesis, and evaluation of axial-chiral biisoquinolines bearing polar aromatic C-H bonds as Lewis base catalysts are reported. Lewis bases containing the 3,5-bis(trifluoromethyl)phenyl group were found to be significantly more enantioselecti

Enantioselective Allyl-, and Allenylboration of Aldehydes Catalyzed by Chiral Hydroxyl Carboxylic Acid

Asymmetric allylboration of aldehydes with allylboronic acid pinacol ester catalyzed by chiral hydroxyl carboxylic acid is described. This reaction provides synthetically useful homoallyl alcohols in high yield with good to high enantioselectivity. The pr

Chiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydes

A series of chiral Lewis bases, phosphine oxide ferrocenyl aziridinyl methanol 1-4, phosphinyl aziridinyl phosphonates 5 and 6, and phosphine oxide aziridinyl phosphonates 7 and 8 were screened for allylsilane additions to aldehydes. Among the Lewis bases

Chiral bis(imidazolinyl)phenyl NCN pincer rhodium(III) Catalysts for enantioselective allylation of aldehydes and carbonyl-ene reaction of trifluoropyruvates

Chiral NCN pincer rhodium(III) complexes with bis(imidazolinyl)phenyl ligands were found to be effective catalysts for the allylation of a variety of electronically and structurally diverse aldehydes with allyltributyltin, giving the corresponding optical

Synthesis of axially chiral C10-BridgePHOS oxides and their use as organocatalysts in enantioselective allylations of aldehydes

A series of C10-BridgePHOS oxides possessing different substituted groups on the diphenyl phosphine system were synthesized and tested as organocatalysts in the allylation of aldehydes with allyltrichlorosilane, providing chiral homoallylic alc

Function oriented synthesis: Preparation and initial biological evaluation of new A-ring-modified bryologs

The synthesis and biological evaluation of the first members of a new series of designed bryostatin A-ring analogues (bryologs) are described. An advanced intermediate is produced that allows for step economical access to diverse analogs. The first of the

Asymmetrie allylation of aldehydes catalyzed by simple dual small organic molecules: L-proline and L-prolinol

A novel and simple methodology for the asymmetric allylation of aldehydes was reported. Double small organic molecules such as L-proline and L-prolinol were first employed for providing a chiral environment so as to afford chiral homoallylic alcohols in high yields and moderate enantioselectivities in our protocol.

6,6′-Bisperfluoroalkylated BINOLs promoted asymmetric allylation of aldehydes

6,6′-Bis1H1H2H2H-perfluoroocty l)-1, 1′-bi-2-naphthol (Rf6-BINOL) and 6,6′-bis(1H, 1H, 2H, 2H-perfluorodecyl)-1,1′-bi-2-naphthol (Rf8-BINOL) were used in allylation of aldehydes in fluorous biphase system. Good enantioselectivity was

A synthetic library of cell-permeable molecules

Small molecules that induce or stabilize the association of macromolecules have proven to be useful effectors of a wide variety of biological processes. To date, all examples of such chemical inducers of dimerization have involved known ligands to well-ch