329950-38-1Relevant academic research and scientific papers
On the phenyliodine(III)-bis(trifluoroacetate)-mediated olefin amidohydroxylation reaction
Tellitu, Imanol,Urrejola, Andrea,Serna, Sonia,Moreno, Isabel,Herrero, M. Teresa,Dominguez, Esther,SanMartin, Raul,Correa, Arkaitz
, p. 437 - 444 (2008/02/03)
When appropriately substituted amides are treated with PIFA in a non-nudeophilic solvent like trifluoroethanol, a stable N-acylnitrenium ion is generated. If under such conditions a C=C double bond is present in the molecule, an intramolecular cyclization
Palladium-catalyzed synthesis of N-aryl pyrrolidines from γ-(N-arylamino) alkenes: Evidence for chemoselective alkene insertion into Pd-N bonds
Ney, Joshua E.,Wolfe, John P.
, p. 3605 - 3608 (2007/10/03)
The formation of a C-C and a C-N bond in a reaction between γ-(N-arylamino) alkenes and aryl bromides results in the stereoselective synthesis of substituted pyrrolidine derivatives (see scheme). Preliminary studies suggest these reactions proceed by intramolecular alkene insertion into the Pd-N bond of intermediate [Pd(Ar)(amido)] complexes. dba = dibenzylideneacetone, dppb = 1,3-bis(diphenylphosphanyl) butane.
Iodine(V) reagents in organic synthesis. Part 1. Synthesis of polycyclic heterocycles via Dess-Martin periodinane-mediated cascade cyclization: Generality, scope, and mechanism of the reaction
Nicolaou,Baran,Zhong,Sugita
, p. 2212 - 2220 (2007/10/03)
The scope, generality, and mechanism of the Dess-Martin periodinane-mediated cyclization reaction of unsaturated anilides discovered during the total synthesis of the CP-molecules (phomoidrides A and B) are delineated. A plethora of heterocyclic compounds
