330477-56-0Relevant academic research and scientific papers
Formation of aryl dialkylphosphinates from dialkylphosphinous chlorides and arylmagnesium bromides under oxidative conditions
Keglevich, Gyoergy,Tamas, Annamaria,Parlagh, Gyula,Toeke, Laszlo
, p. 38 - 41 (2007/10/03)
The reaction of dialkylphosphinous chlorides (1) with arylmagnesium bromides carried out in the air atmosphere was found to afford aryl-dialkylphosphine oxides (2) and aryl dialkylphosphinates (3) in a comparable quantity. Formation of the latter product (3) is the first example that an aryl-dialkylphosphine, formed as an intermediate, is autooxidized to the corresponding phosphinate.
