33053-06-4Relevant articles and documents
A dinuclear palladium catalyst for α-Hydroxylation of carbonyls with O2
Chuang, Gary Jing,Wang, Weike,Lee, Eunsung,Ritter, Tobias
supporting information; experimental part, p. 1760 - 1762 (2011/04/15)
A chemo- and regioselective α-hydroxylation reaction of carbonyl compounds with molecular oxygen as oxidant is reported. The hydroxylation reaction is catalyzed by a dinuclear Pd(II) complex, which functions as an oxygen transfer catalyst, reminiscent of an oxygenase. The development of this oxidation reaction was inspired by discovery and mechanism evaluation of previously unknown Pd(III)-Pd(III) complexes.
Chemical synthesis of phenylbutazone hydroperoxide and investigation of the drug for cardiac action under in vitro and in vivo conditions
Mentz,Schulz,Kluge
, p. 1229 - 1232 (2007/10/02)
Phenylbutazone (4-n-butyl-1,2-diphenyl-pyrazolidine-3,5-dione) 1 is an easily autoxidable substance which forms a crystalline and stable hydroperoxide 3. The decomposition of 3 yields products which were investigated as metabolites of the drug. In isolate