330587-67-2Relevant articles and documents
Surprising diversity of non-classical silicon-hydrogen interactions in half-sandwich complexes of Nb and Ta: M-H ... Si-Cl interligand hypervalent interaction (IHI) versus stretched and unstretched β-Si-H...M agostic bonding
Nikonov, Georgii I.,Mountford, Philip,Ignatov, Stanislav K.,Green, Jennifer C.,Leech, Michael A.,Kuzmina, Lyudmila G.,Razuvaev, Alexei G.,Rees, Nicholas H.,Blake, Alexander J.,Howard, Judith A.K.,Lemenovskii, Dmitry A.
, p. 2903 - 2915 (2007/10/03)
Reaction of the niobium diphosphine compound [NbCp(NAr)(PMe3)2] (Ar = 2,6-C6H3Pr2i) with HSiMe2Cl gives the formally d2 silylamido derivative [NbCp{η3-N(Ar)