330598-54-4Relevant academic research and scientific papers
Carbon-carbon bond forming reactions of N-bound transition metal α-cyanocarbanions: A mechanistic probe for catalytic Michael reactions of nitriles
Naota,Tannna,Murahashi
, p. 63 - 64 (2007/10/03)
N-Bound α-cyanocarbanion complexes Ru+Cp(NCCH-R1)(PPh3)2 1 react with electron deficient olefins to afford the conjugate adduct Ru+Cp(NCC-R1CHR2CR3R4) (PPh3)2 2, kinetic studies of which revealed that complex 1-catalyzed Michael reactions of nitriles proceed via transformation of 1 to 2 and subsequent ligand exchange with nitriles.
