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• 129353-70-4 phenyl tris(N,N,N′-trimethylethylenediamino)-silane 

Relevant academic research and scientific papers

Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex

The reaction of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dmpe)(PEt3)2(dmpe?=?Me2PCH2CH2PMe2) in the ratio of 1:1 yields the complex {1,2-C6H4(SiMe2)(SiH2)}PtII(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis)silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 lead

Isolation of a bis(silyl)palladium complex and Si–Si bond formation on a mononuclear palladium complex

Treatment of a chelating silane 1-(dimethylsilyl)-2-silylbenzene (4) with Pd(PEt3)4 in the ratio of 2:1 selectively afforded a unique mononuclear palladium complex [{1,2-C6H4(SiMe2)(SiH)}2Pd(PEt3)2] (6), which was formed by two Si–Si coupling reactions between the SiH2 groups and the SiMe2 moieties from two hydrosilane ligands. Complex 6 was structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies and is one of the very few examples of cis-bis(silyl)palladium(II) complexes containing in situ formed Si–Si single bonds.

Reaction of 1-(dimethylsilyl)-2-silylbenzene with platinum(0) phosphine complex: Isolation and characterization of the Si3-PtIV-H complex

Reaction of two equivalents of 1,2-C6H4(SiMe 2H)(SiH3) with Pt(depe)(PEt3)2 (depe = Et2PCH2CH2PEt2) in toluene at room temperature afforded two n

Isolation of two bis(silyl)nickel complexes with Si-Si bond formation in a single-crystal-to-single-crystal fashion

A unique penta-coordinate nickel complex [{1,2-C6H4(SiMe2)(SiH)}2Ni(PEt3)(depe)] (6) that generates two new Si-Si single bonds has been prepared exclusively by the reaction of a chelating silyl hydride 1-(dimethylsilyl)-2-silylbenzene (4) and Ni(depe)(PEt3)2 (depe = Et2PCH2CH2PEt2) in a 2:1 ratio. Complex 6 is the first example of mononuclear silyl nickel complexes containing a Si-Si single bond formed in situ. Interestingly, framework 6 exhibits reversible single-crystal-to-single-crystal transformations upon the removal and rebinding of the coordinating PEt3 molecule, which give rise to a PEt3-free complex [{1,2-C6H4(SiMe2)(SiH)}2Ni(depe)] (6′), concomitant with the alteration of the coordination geometry of central metal atoms.