330813-55-3Relevant academic research and scientific papers
Preparation of an aliphatic-substituted hypervalent iodine compound, tetracoordinate 1,2-iodoxetane 1-oxide, and its application to oxidation
Kano, Naokazu,Ohashi, Masaki,Hoshiba, Kazuhisa,Kawashima, Takayuki
, p. 8173 - 8175 (2004)
A tetracoordinate 1,2-iodoxetane oxide was prepared, and it oxidized alcohols to the corresponding aldehydes and ketones in good to moderate yields under mild conditions. A tetracoordinate 1,2-iodoxetane was prepared by the fluorination of a tricoordinate 1,2-iodoxetane with xenon difluoride followed by hydrolysis. The tetracoordinate 1,2-iodoxetane oxidized alcohols and a sulfide to the corresponding aldehydes and ketones, and a sulfoxide, respectively, in good to moderate yields under mild conditions.
