3309-79-3Relevant articles and documents
REACTIVITE DE CARBANIONS &β CETOPHOSPHOROTHIOLATE REARRANGEMENT PHOSPHOROTHIOLATE-PHOSPHATE D'ENOL
Sturtz, G.,Baboulene, M.
, p. 3067 - 3070 (2007/10/02)
The stabilization of S-alkanoate O,O-dialkyl phosphates carbanions has been tried.An enol phosphate-phosphorothiolate rearrangement is observed and the mechanism is described.This new transposition has been applied to the synthesis of various enol phosphates with thioether of enol function of phytosanitaire interest.