331472-63-0Relevant academic research and scientific papers
Fine-tuning electrophilicity of cationic tricarbonyliron complexes
Malkov, Andrei V.,Stephenson, G. Richard
, p. C44 - C47 (1995)
Solvent effects can be used to switch aryllithium addition to η5-cyclohexadienyl tricarbonyliron complexes between novel formation of an acyl product, and the synthetically more valuable direct addition to the dienyl ligand.This gives efficient
Addition of aryl substituants to cyclohexadienyliron electrophiles in the development of routes to C12 central building blocks for alkaloid synthesis
Malkov, Andrej V.,Auffrant, Audrey,Renard, Christophe,Rose, Eric,Rose-Munch, Franc?oise,Owen, David A.,Sandoe, Elizabeth J.,Stephenson, G. Richard
, p. 139 - 149 (2008/10/08)
Novel iron-aroyl complexes or synthetically prized arylcyclohexadienyl complexes can be formed from tricarbonyl(η5-1,4-dimethoxycyclohexadienyl)iron(1 +) hexafluorophosphate(1-) by correct control of reaction sequences that exploit the addition of aryllithium reagents to introduce the aromatic group. Bimetallic products are obtained when a tricarbonylchromium-bound aryllithium reagent or the corresponding cuprate are employed.
