33152-37-3

Upstream product

• 108-86-1 bromobenzene 
• 1190113-71-3 [Co(4-CF₃-C₆F₄)(trimethylphosphine)3] 
• 594-09-2 trimethylphosphane 

Downstream Products

• 2404-55-9 trimethylphosphane sulfide 
• 20819-54-9 trimethylphosphane selenide 
• 260975-57-3 [(1,2-diphenyl-2-oxo-ethene-1-yl)carbonyl]tris(trimethylphosphine)nickel 
• 911037-04-2 Co(C₆H₃F₂)(CN)(P(CH₃)3)3 
• 953089-65-1 [mer-Co(H)(SPh)2(PMe₃)3] 
• 1190113-68-8 [Co(4-CF3-η2-C6F3)(trimethylphosphine)3] 
• 1190113-71-3 [Co(4-CF₃-C₆F₄)(trimethylphosphine)3] 
• 1314384-61-6 [(Me3P)Co(η5-C5H4PPh2)]2 
• 1314384-77-4 [(1,1'-bis(diphenylphosphino)ferrocene)Co(PMe₃)2] 
• 1384754-97-5 [(C₆H₄C(O)NC₆H₄-4-Cl)Co(III)(Cl-ortho-C₆H₄C(O)NC₆H₄-4-Cl)(trimethylphosphine)2] 
• 1384754-96-4 [(C₆H₄C(O)NC₆H₄-4-Me)Co(III)(Cl-ortho-C₆H₄C(O)NC₆H₄-4-Me)(trimethylphosphine)2] 
• 1384754-95-3 [(C₆H₄C(O)NPh)Co(III)(Cl-ortho-C₆H₄C(O)NPh)(trimethylphosphine)2] 
• 1429229-77-5 [cobalt(II)tetrakis(trimethylphosphine)(pentafluorophenyl)(hydride)] 
• 327-54-8 1,2,4,5-Tetrafluorobenzene 

Relevant academic research and scientific papers

Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II) Imido Complexes [(Me3P)3Co(NAr)]

The reactions of [Co(PMe3)4] with the bulky organic azides, DippN3 and DmpN3 [Dipp, 2,6-diisopropylphenyl; Dmp, 2,6-di(2′,4′,6′-trimethylphenyl)phenyl], afforded the cobalt(II) terminal imido complexes [(Me3P)3Co(NAr)] (Ar = Dipp, 1; Dmp, 2). The cobalt imido complexes in their solid states show trigonal pyramidal coordination geometry and long Co-N(imido) separations (ca. 1.71 ?). Spectroscopic characterization and theoretical studies indicated their low-spin cobalt(II) nature. Reactivity studies on 1 revealed its nitrene-transfer reactions with PMe3 and CO, the imido/oxo and imido/sulfido exchange reactions with PhCHO and CS2, and the single-electron oxidation reaction by ferrocenium cation to form cobalt(III) imide.

Synergistic effect of a low-valent cobalt complex and a trimethylphosphine ligand on selective c-f bond activation of perfluorinated toluene

The aryne cobalt complex [Co(4-CF3-η2-C6F 3)(PMe3)3] (1) was formed from the reaction of [Co(PMe3)4] and perfluorinated toluene through selective activation of two C-F bonds of perfluorotol