33156-03-5

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 108-24-7 acetic anhydride 
• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 

Downstream Products

• 77735-47-8 Acetic acid (2R,3S,4R)-4-acetoxy-2-(bis-benzylsulfanyl-methyl)-tetrahydro-thiophen-3-yl ester 
• 77735-56-9 4-O-acetyl-2,5-epithio-3-S-benzyl-3-thio-D-ribose dibenzyl dithioacetal 
• 1202373-16-7 2-O-(2-acetoxyisopropyl)-1,3-di-O-acetyl-5-O-p-toluenesulfonyl-β-D-xylofuranoside 

Relevant academic research and scientific papers

Novel chiral xylofuranose-based phosphinooxathiane and phosphinooxazinane ligands for palladium-catalyzed asymmetric allylations

Novel chiral xylofuranose-based phosphinooxathiane and phosphinooxazinane ligands were found to provide high levels of enantioselectivity (up to 94% ee) in palladium-catalyzed asymmetric allylic alkylations and aminations.

Novel chiral xylofuranose-based phosphinooxathiane and phosphinooxazinane ligands for palladium-catalyzed asymmetric tandem allylic allylation

Novel chiral xylofuranose-based phosphinooxathiane and phosphinooxazinane ligands have been synthesized and found to be effective ligands for palladium-catalyzed asymmetric tandem allylic allylations of 1,4-diacetoxy-cis-2-butene with 2-(benzylamino)ethanol or 1,2-bis[benzylamino]ethane to give chiral 4-benzyl-2-vinylmorpholine (94% ee) or 1,4-dibenzyl-2-vinylpiperazine (70% ee).