331680-14-9Relevant academic research and scientific papers
Toward organometallic polymers with high directionality containing bis-ortho-chelating ligands
Back, Stephan,Albrecht, Martin,Spek, Anthony L.,Rheinwald, Gerd,Lang, Heinrich,Van Koten, Gerard
, p. 1024 - 1027 (2001)
The preparation and structure of the rigid rod-like platinum monoacetylide {Pt}C≡C-4-C6H2I-1-((CH2 NMe2)2-2,6) ({Pt} = [Pt(C6H3 {Me2NCH2}2-2,6)]) are described. Its oxidative addition to Pd(dba)2 yields a heterobinuclear {Pt}C≡C{Pd}I complex ({Pd} = [Pd(-4-C6H2{Me2 NCH2}2-2,6)]+) this provides a new strategy for the controlled and stepwise construction of rigid rod-like metallopolymers.
