331687-32-2Relevant academic research and scientific papers
(Diazomethyl)silyl-functionalized Fischer-type carbene complexes
Maas, Gerhard,Mayer, Dieter
, p. 339 - 345 (2007/10/03)
The synthesis of two types of so far unknown title compounds is described. Carbene complexes LnM=C(R)O-SiR2-C(N2)COOMe [LnM=(OC)5W (3), (OC)5Cr (4), (OC)5Mo (5), (MeCp)(OC)2Mn (6)] were obtained from the corresponding acyl metalates by electrophilic (diazomethyl)silylation. Similarly, (diazomethyl)silylation of lithiated dicarbonyl(η 5-methylcyclopentadienyl)(1-ethoxyethylidene)manganese yielded a manganese carbene complex (8a) with CH2-SiR2-C(N2)COOMe substitution.
