331812-02-3Relevant academic research and scientific papers
Synthesis of α, α′-asymmetric nitroxide radicals by C- or O-acylation of radical-enolate intermediates generated by reduction of homoallylic nitro enones with samarium(II) iodide
Tamura, Rui,Shimono, Satoshi,Fujita, Kasuke,Hirao, Ken-Ichi
, p. 217 - 224 (2007/10/03)
A new synthetic method to form two structurally different α, α′-asymmetric bicyclic nitroxides from the same substrate is described. Reduction of certain homoallylic nitro enones bearing a long alkyl chain with 3.0 equiv of SmI2 in THF at -78°C
