331822-05-0

Basic information

• Product Name: Prop-2-en-1-yl 3-oxo-5-(2,6,6-trimethylcyclohex-1-en-1-yl)pentanoate
• Synonyms: Prop-2-en-1-yl 3-oxo-5-(2,6,6-trimethylcyclohex-1-en-1-yl)pentanoate
• CAS NO: 331822-05-0
• Molecular Weight: 278.392
• Mol File: 331822-05-0.mol

Chemical Properties

• CAS DataBase Reference: Prop-2-en-1-yl 3-oxo-5-(2,6,6-trimethylcyclohex-1-en-1-yl)pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: Prop-2-en-1-yl 3-oxo-5-(2,6,6-trimethylcyclohex-1-en-1-yl)pentanoate(331822-05-0)
• EPA Substance Registry System: Prop-2-en-1-yl 3-oxo-5-(2,6,6-trimethylcyclohex-1-en-1-yl)pentanoate(331822-05-0)

Safety Data

• Hazardous Substances Data: 331822-05-0(Hazardous Substances Data)

Upstream product

• 15022-08-9 diallylcarbonate 
• 17283-81-7 4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on 
• 59633-89-5 3-oxo-5-(2,6,6-trimethyl-cyclohex-1-enyl)-pentanoic acid methyl ester 
• 107-18-6 allyl alcohol 
• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 
• 472-20-8 β-cyclogeraniol 
• 79-77-6 (E)-β-ionone 
• 59633-88-4 2-(bromomethyl)-1,3,3-trimethylcyclohex-1-ene 

Downstream Products

• 331822-06-1 Prop-2-en-1-yl 2-[2-(2,6,6-trimethylcyclohex-1-en-1-yl)ethyl]-4-oxo-4H-1-benzopyran-3-carboxylate 

Relevant articles and documents

A conjugate addition-radical cyclisation approach to sesquiterpene-phenol natural products

A conjugate addition-radical cyclization approach to sesquiterpenephenol natural products was discussed. The first step involved the conjugate addition of an organocopper species to a chromone-3-carboxylate which resulted in 2,2-disubstituted chroman-4-ones. The second step was the generation of a β-ketoester radical. The last step involved a stereoselective manganese(III) acetate-mediated radical cyclization reaction.