3319-31-1Relevant articles and documents
PLASTICIZER COMPOSITION AND RESIN COMPOSITION INCLUDING THE SAME
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Paragraph 0119-0120; 0127, (2021/07/31)
Provided is a plasticizer composition including: a cyclohexane-1,2-diester-based substance of the following Chemical Formula 1; and a citrate-based substance of the following Chemical Formula 2: wherein in Chemical Formula 1 and Chemical Formula 2: R1 and R2 each independently are a C8 to C10 alkyl group; and R3 to R5 each independently are a C5 to C10 alkyl group.
Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
Tashi, Maryam,Shafiee, Behnaz,Sakamaki, Yoshie,Hu, Ji-Yun,Heidrick, Zachary,Khosropour, Ahmad R.,Beyzavi, M. Hassan
, p. 37835 - 37840 (2018/11/26)
The combination of continuous flow technology with immobilizing of only 0.13?mol% of triflic acid (TfOH) on silica-encapsulated superparamagnetic iron oxide nanoparticles (SPIONs) under solvent-free conditions successfully provided a powerful, efficient, and eco-friendly route for the synthesis of plasticizers. The turnover frequency value in micro-flow conditions varied in the range of 948.7 to 7384.6 h?1 compared to 403.8 to 3099 h?1 for in-flask. This technique works efficiently, encouraging future applications of micro-flow nano-catalysis in green chemistry.
Method for synthesizing trimellitic triesters
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Paragraph 0023; 0027; 0028; 0029; 0030-0032; 0035-0039, (2017/04/26)
The invention discloses a method for synthesizing trimellitic triesters. The method comprises the following steps: carrying out a methyl esterification reaction on trimellitic anhydride light and heavy components and methanol used as raw materials under the catalysis of a catalyst to generate trimethyl trimellitate, rectifying the trimethyl trimellitate to obtain high-purity and low-color number trimethyl trimellitate, and carrying out ester exchange on trimethyl trimellitate and 2-ethylhexanol, and purifying the obtained ester exchange product to obtain a tri(2-ethylhexyl) trimellitate product. The method has the advantages of effective recycling of the trimellitic anhydride light and heavy components, reduction of generation of pollutants, increase of economic benefits, reduction of the product cost and the environmental protection pressure, low requirements of the content and the color number of the raw material trimellitic anhydride, and realization of high content and low color number of obtained trihexyl ester, and allows the quality of the trihexyl ester to be better than the quality of trihexyl ester obtained through direct esterification of trimellitic anhydride and 2-ethylhexanol.