3319-46-8Relevant academic research and scientific papers
GENERAL SYNTHESIS OF POLYSUBSTITUTED THIOPHENES FROM DIKETO SULFIDES
Nakayama, Juzo,Machida, Haruki,Saito, Ryuji,Hoshino, Masamatsu
, p. 1983 - 1984 (2007/10/02)
Treatment of diketo sulfides with a low-valent titanium reagent at 0 deg C (in two cases at room temperature) affords 3,4-dihydroxythiolanes in good yields.The acid-catalyzed (p-toluenesulfonic acid) dehydration of the latter compounds leads to the corres
GENERAL SYNTHESIS OF 2,5-DIHYDROTHIOPHENES (3-THIOLENES) FROM DIKETO SULFIDES
Nakayama, Juzo,Machida, Haruki,Hoshino, Masamatsu
, p. 1981 - 1982 (2007/10/02)
The intramolecular reductive coupling reaction of easily accesible diketo sulfides by a low-valent titanium reagent (prepared from titanium(IV) chloride and zinc powder) provides an efficient general synthesis of 2,5-dihydrothiophenes.
