332041-60-8Relevant articles and documents
BINAP/AgOTf/KF/18-crown-6 as new bifunctional catalysts for asymmetric Sakurai-Hosomi allylation and Mukaiyama aldol reaction
Wadamoto, Manabu,Ozasa, Nobuko,Yanagisawa, Akira,Yamamoto, Hisashi
, p. 5593 - 5601 (2003)
A catalytic amount of KF·18-crown-6 complex is effective as a soluble fluoride source to activate an asymmetric Sakurai-Hosomi allylation with BINAP and silver(I) triflate catalyst. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic al
Chiral base-catalyzed aldol reaction of trimethoxysilyl enol ethers: Effect of water as an additive on stereoselectivities
Orito, Yuya,Hashimoto, Shunichi,Ishizuka, Tadao,Nakajima, Makoto
, p. 390 - 400 (2007/10/03)
An aldol reaction of trimethoxysilyl enol ether catalyzed by lithium binaphtholate is described. The aldol reaction of trimethoxysilyl enol ether derived from cyclohexanone under anhydrous conditions predominantly afforded the anti-aldol adduct with moder
Enantioselective aldol reaction of trimethoxysilyl enol ethers with aldehydes catalyzed by p-Tol-BINAP·AgF complex
Yanagisawa,Nakatsuka,Asakawa,Kageyama,Yamamoto
, p. 69 - 72 (2007/10/03)
New catalytic asymmetric Mukaiyama-type aldol reaction using trimethoxysilyl enol ethers was achieved using p-Tol-BINAP·AgF complex as a catalyst. High syn- and enantioselectivities were obtained both from the E- and Z-silyl enol ethers.