332095-62-2

Upstream product

• 332095-59-7 12-((tert-butyldiphenylsilyl)oxy)dodecanal 
• 166170-71-4 12-((tert-butyldiphenylsilyl)oxy)dodecan-1-ol 
• 332095-61-1 methyl E-14-(tert-butyldiphenylsilyloxy)-3-tetradecenoate 
• 332095-60-0 (4S,5S)-5-[10-(tert-butyldiphenylsilyloxy)decyl]-4,5-dihydro-4-hydroxy-2(3H)-furanone 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 5675-51-4 1,12-dodecandiol 

Downstream Products

• 332095-64-4 (4S,5S)-4-[10-(tert-butyldiphenylsilyloxy)decyl]-2,2-dimethyl-5-(2-iodoethyl)-1,3-dioxolane 
• 332095-66-6 (4S,5S)-Z,Z-4-[10-(tert-butyldiphenylsilyloxy)decyl]-5-(3,7-eicosadienyl)-2,2-dimethyl-1,3-dioxolane 
• 332095-63-3 (4'S,5'S)-2-{5-[10-(tert-butyldiphenylsilyloxy)decyl]-2,2-dimethyl-1,3-dioxolan-4-yl}ethanol 

Relevant academic research and scientific papers

Elucidation of the stereostructure of the annonaceous acetogenin (+)-montecristin through total synthesis

Total syntheses of ent-5-epi-montecristin (1a) and of (-)-montecristin (1b) were accomplished. The stereocenters of compounds 1a and 1b were established by asymmetric dihydroxylations of the trans-configurated β,γ-unsaturated esters 6 (→4, up to 80% ee; S