332113-78-7

Basic information

• Product Name: 5-(4-Methylphenyl)thiazole
• Synonyms: 5-(4-Methylphenyl)thiazole
• CAS NO: 332113-78-7
• Molecular Weight: 175.254
• Mol File: 332113-78-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 5-(4-Methylphenyl)thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(4-Methylphenyl)thiazole(332113-78-7)
• EPA Substance Registry System: 5-(4-Methylphenyl)thiazole(332113-78-7)

Safety Data

• Hazardous Substances Data: 332113-78-7(Hazardous Substances Data)

Upstream product

• 288-47-1 1,3-thiazole 
• 106-38-7 para-bromotoluene 
• 624-31-7 4-tolyl iodide 
• 619-41-0 4-(bromoacetyl)toluene 
• 127118-89-2 C₁₁H₁₁NO₃ 

Downstream Products

• 882182-72-1 2-phenylsulfanyl-5-p-tolyl-thiazole 
• 6071-54-1 5-(4-methylphenyl)-2-phenylthiazole 
• 4271-09-4 2,2'-benzothiazolyl 
• 1398308-29-6 2-(5-(p-tolyl)thiazol-2-yl)benzo[d]thiazole 
• 1388625-47-5 2-(5-p-tolylthiazol-2-yl)benzoxazole 
• 1339019-86-1 (E)-2-(oct-4-en-4-yl)-5-(4-tolyl)thiazole 

Relevant articles and documents

Colourless p-phenylene-spaced bis-azoles for luminescent concentrators

We report on the synthesis of new push-pull imidazole-benzothiazole and thiazole-benzothiazole fluorophores obtained in good yields by using direct C-H arylation synthetic strategies. Spectroscopic investigations in CHCl3 solution evidenced that the 1,4-phenylene-spaced imidazole-benzothiazole bearing an electron-donating dimethylamino group achieved a trade-off between fluorescence maximum (516 nm), Stokes shift (165 nm) and a quantum yield higher than 0.4. Dispersions of the selected fluorophore in poly (methyl methacrylate) (PMMA) thin films mostly maintained the optical features in solution with significant light transmittance in the visible region (90% at 440 nm), and a brilliant green emission at 500 nm. Photocurrent experiments performed on PMMA thin films coated over high purity transparent glasses promoted their use in the development of colourless luminescent solar concentrators with optical efficiencies close to 6%.

Mild palladium-catalyzed regioselective direct arylation of azoles promoted by tetrabutylammonium acetate

A mild, general, and convenient palladium-catalyzed direct arylation of the 5-position of azoles with aryl bromides, efficiently promoted by tetrabutylammonium acetate, is described. 1-Methylpyrazole, oxazole, and thiazole reacted at 70°C in N,N-dimethyla

Direct arylation reactions catalyzed by Pd(OH)2/C: Evidence for a soluble palladium catalyst

Palladium hydroxide on carbon (Pearlman's catalyst) effectively catalyzes direct arylation reactions of aryl iodides and bromides, providing excellent arylation-to-hydrodehalogenation ratios (>30:1) with broad scope for both intra- and intermolecular arylation processes. Studies aimed at determining the nature of the active catalyst indicate that an active homogeneous palladium species is produced under the reaction conditions.