33294-37-0Relevant academic research and scientific papers
Orthometalated amino-carbene derivatives of iridium via anilines and terminal alkynes
Kumaran, Elumalai,Sridevi, Venugopal Shanmugham,Leong, Weng Kee
, p. 6417 - 6421 (2010)
The reaction of a terminal alkyne (RCCH) and an aniline (R′C 6H4NH2) with the dinuclear species [Cp*IrCl2]2 afforded cyclometalated amino-carbene derivatives Cp*Ir(Cl)[=C(CH2R)NHC6H 3R′] via a hydroamination and an orthometalation. The reaction pathway has been examined through deuterium labeling and computational studies.
