33297-29-9Relevant academic research and scientific papers
Heteroarylboronates in rhodium-catalyzed 1,4-addition to enones
Albrecht, Fabian,Sowada, Oliver,Fistikci, Meryem,Boysen, Mike M.K.
, p. 5212 - 5215 (2014)
Rhodium(I)-catalyzed 1,4-addition of aryl and alkenylboronic acids to α,β-unsaturated carbonyl compounds is well established, but the transfer of heteroaryl residues in this reaction remains underdeveloped. We have studied heteroaryl MIDA and pinacol boro
Conjugate Michael additions with mixed diorganozincs
Jones, Philip,Kishan Reddy,Knochel, Paul
, p. 1471 - 1490 (2007/10/03)
Functionalised mixed alkyl(trimethylsilylmethyl)zinc reagents add efficiently to a wide variety of Michael acceptors in high yield and with exclusive 1,4-regioselectivity, without the need for transition metal catalysis. The trimethylsilylmethyl group behaves as a non-transferable group, and in no cases was transfer of this group observed.
REACTIONS OF HIGHER ORDER CYANOCUPRATES DERIVED FROM 2-LITHIATED FURANS: SCOPE, LIMITATIONS, AND SYNTHETIC UTILITY
Ng, John S.,Behling, James R.,Campbell, Arthur L.,Nguyen, Duy,Lipshutz, Bruce
, p. 3045 - 3048 (2007/10/02)
A general study on the chemistry of higher order organocuprates derived from 2-lithiated furans with enones, epoxides, aldehydes and halides is described.
