3330-15-2Relevant articles and documents
A NEW METHOD FOR ELIMINATING CARBONYL FLUORIDE FROM α-TRIFLUOROMETHYLATED ACYL FLUORIDES
Ohsaka, Yohnosuke,Amimoto, Yoshio,Takaki, Shoji
, p. 54 (1982)
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Polyfluorinated ethers: IV.* By-products in the synthesis of polyfluorinated alkyl vinyl ethers in a solvating solvent
Yuminov
, p. 1715 - 1720 (2007/10/03)
By-products formed in the synthesis of perfluoro(propyl vinyl ether), perfluoro(2-propoxypropyl vinyl ether), and methyl perfluoro(4-vinyloxybutanoate) in a solvating solvent have been studied. 1998 MAHK "Hayka/Interperiodica".
DIPHOSPHATETRAAZACYCLOOCTATETRAENES. II. PROPERTIES AND DEGRADATIONS
Paciorek, K. J. L.,Ito, T. I.,Nakahara, J. H.,Kratzer, R. H.
, p. 441 - 450 (2007/10/02)
1,5-Bis(diphenylphospha)-3,7-bis(perfluoroalkylether)-2,4,6,8-tetraazacyclooctatetraene and 1,3-bis(diphenylphospha)-5,7-bis(perfluoroalkylether)-2,4,6,8-tetraazacyclooctatetraene were found to decompose at 316 deg C to phospha-s-triazines.The symmetrical arrangement liberated perfluoroalkylether nitrile with concommitant formation of the corresponding diphospha-s-triazine; the unsymmetrical isomer eliminated the (C6H5)2PN unit to give the monophospha-s-triazine.The thermal and oxidative stabilities of the two compounds differed widely with the unsymmetrical isomer being significantly more stable than the symmetrical arrangement.Spectral data pertinent to these results are discussed.Both materials were found to be effective in arresting perfluoroalkylether fluid degradation in oxidizing atmospheres in the presence of metal alloys.