33301-74-5Relevant academic research and scientific papers
STUDIEN ZUM VORGANG DER WASSERSTOFFUEBERTRAGUNG 62. HERSTELLUNG UND ELEKTROREDUKTIVE SPALTUNG EINIGER ARYLDISULFONSAEUREDERIVATE
Horner, Leopold,Schmitt, Rolf-Elhard
, p. 169 - 178 (2007/10/02)
Benzene-disulfonylchlorides were converted to the corresponding dialkyl- and diphenylesters, N-alkyl- and N-aryl disulfonamides.The half-wave-potentials E11/2 and E21/2 were measured and the products obtained on potentiostatic fission at E11/2 were isolated and characterized.The electroreduction of benzene-1,4-disulfonic acid-diphenylester in methanol yields phenol in quantity approximately corresponding to the current passed, but no corresponding quantity of sulfinic acid.In dry acetonitrile, benzene-1,4-disulfonic acid diesters and diamides undergo potentiostatic fission (at E11/2) in good chemical and current yields, giving the corresponding monosulfonate-sulfinic acid or monosulfonamide-sulfinic acid and alcohol or amine.The passage of further electrical current reduces the sulfinic acids to other, as yet undetermined, products.
