333380-75-9Relevant academic research and scientific papers
Aluminum-controlled reactivity and diastereoselectivity toward radical reactions of optically active aldimines with metallic samarium
Yanada,Okaniwa,Kaieda,Ibuka,Takemoto
, p. 1283 - 1286 (2001)
The intermolecular pinacol-type coupling reaction and allylation reaction of optically active imines bearing a β-hydroxy group were performed stereoselectively with metallic samarium after treatment of the imines with trimethylaluminum.
Samarium-promoted diastereoselective reductive coupling of optically active imines
Yanada, Reiko,Negoro, Nobuyuki,Okaniwa, Masanori,Miwa, Yoshihisa,Taga, Tooru,Yanada, Kazuo,Fujita, Tetsuro
, p. 537 - 540 (2007/10/03)
The intermolecular pinacol-like coupling of optically active imines was performed stereoselectively with metallic samarium and a catalytic amount of iodine to give chiral C2-2,2'-ethylenediimino-diethanol derivatives.
