33354-61-9Relevant academic research and scientific papers
A Synthetic Approach to Azepin-4-ones exploiting Azide Photolysis in Low-temperature Matrices
Dunkin, Ian R.,Ayeb, Abdunaser El,Lynch, Michael A.
, p. 1695 - 1696 (1994)
Photolysis of 2,6-dichloro-4-azidophenol and 2,6-dibromo-4-azidophenol in N2 or Ar matrices at 12-14 K results in ring expansion, yielding in each case either the corresponding hydroxydidehydroazepine or, in more concentrated matrices, the tautomeric azep
4H-Azepin-4-ones from 4-azidophenols in low-temperature matrices
Dunkin, Ian R.,El Ayeb, Abdunaser A.,Gallivan, Sean L.,Lynch, Michael A.
, p. 1419 - 1427 (2007/10/03)
In an attempt to develop a synthetic approach to 4H-azepin-4-ones in exceptionally mild conditions, 4-azidophenols have been photolysed in N2 matrices at 12-14 K and subjected to flash vacuum pyrolysis (FVP) with subsequent trapping of the prod
