333725-83-0Relevant academic research and scientific papers
Unexpected products from the formylation of N,N-dimethylanilines with 2-formamidopyridine in POCl3
Cheng, Ying,Jiao, Peng,Williams, David J.,Cohn, Otto-Meth
, p. 44 - 46 (2007/10/03)
The formation of unexpected products from the formylation of N,N-dimethylanilines with 2-formamidopyridine in POCl3 was discussed. The reaction led to the formation of a product derived from two units of the t-aniline and one of the pyridine with less four protons. The formation of these products was due to the oxidation of one of the methyl groups of an N,N-dimethyl-aniline moiety, a process which is initiated by a 't-amino effect' interaction.
